1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name	:	OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT (REG NO 22258 P.C.P. ACT) 
	
Use of the Substance/Mixture	:	Insect Repellent
	
Company	:	S.C. Johnson and Son, Limited
1 Webster Street
Brantford   ON   N3T 5R1
  	
Emergency telephone number	:	 24 Hour Transport & Medical Emergency Phone (866) 231-5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666

2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor	:	clear / liquid / pleasant	

Immediate Concerns
	:	Warning
FLAMMABLE:
CAUSES EYE IRRITATION.
Keep away from heat, sparks and flame.
Avoid contact with eyes and lips.
May be harmful if swallowed.

Potential Health Effects
Exposure routes	:	Eye, Skin, Inhalation, Ingestion. 
	
Eyes	:	Causes: 
Moderate eye irritation 
	
Skin	:	May cause skin reactions in rare cases. 
	
Inhalation	:	May cause nose, throat, and lung irritation. 
Inhalation may cause central nervous system effects. 
	
Ingestion	:	Causes headache, drowsiness or other effects to the central nervous system. 
May be harmful if swallowed. 
	
Aggravated Medical Condition	:	Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects 
Do not apply to cuts or irritated skin. 

3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:

Chemical Name	CAS-No.	Weight percent	
Ethyl alcohol	64-17-5	 30.00 - 60.00	
N,N-Diethyl-m-toluamide	134-62-3	 10.00 - 30.00	

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES
Eye contact	:	Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. 
	
Skin contact	:	Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing. 
	
Inhalation	:	Remove to fresh air. 
	
Ingestion	:	If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 

5. FIREFIGHTING MEASURES
Suitable extinguishing media	:	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.	

Specific hazards during firefighting	:	Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Burns with colourless flame. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. 	

Further information	:	Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 	

Flash point	:	28.8 °C
83.84 °F
	
Lower explosion limit	:	Note: no data available
	
Upper explosion limit	:	Note: no data available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions	:	Remove all sources of ignition.
Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Wear personal protective equipment.
	
Environmental precautions	:	Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental contamination.
Outside of normal use, avoid release to the environment.
	
Methods for cleaning up	:	Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

7. HANDLING AND STORAGE
Handling
Advice on safe handling	:	Avoid contact with eyes and lips.
Avoid breathing vapours, mist or gas.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Smoking, eating and drinking should be prohibited in the application area.
	
Advice on protection against fire and explosion	:	Keep away from heat and sources of ignition.
Take measures to prevent the build up of electrostatic charge.

Storage
Requirements for storage areas and containers	:	Keep away from food, drink and animal feedingstuffs.
Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.
	
Storage Stability	:	Stable under recommended storage conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components	CAS-No.	mg/m3
 	ppm 
	Non-standard units	Basis	
Ethyl alcohol	64-17-5	-
1,000 ppm
	-
	ACGIH STEL

Personal protective equipment
Respiratory protection
		Use only with adequate ventilation.
 Do not spray in enclosed areas.
	
Hand protection
	:	No special requirements.
	
Eye protection
	Safety glasses with side-shields
	
Skin and body protection
:	No special requirements.
	
Hygiene measures	:	Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. 

9. PHYSICAL AND CHEMICAL PROPERTIES
Form	:	liquid
	
Color	:	clear
	
Odor	:	pleasant
	
pH 	:	5.3
	
Boiling point	:	no data available
	
Freezing point	:	no data available
	
Flash point	:	28.8 °C
83.84 °F
	
Evaporation rate	:	no data available
	
Flammability (solid, gas) 	:	Sustains combustion
	
Auto-ignition temperature 	:	no data available
	
Lower explosion limit	:	no data available
	
Upper explosion limit	:	no data available
	
Vapour pressure	:	no data available
	
Density	:	0.93 g/cm3
at 21 °C	
Water solubility	:	soluble
	
Partition coefficient: n-octanol/water	:	
no data available
	
Viscosity, dynamic	:	no data available
	
Viscosity, kinematic	:	no data available
	
Volatile Organic Compounds 
Total VOC (wt. %)*	:	35.7 %	- additional exemptions may apply
*as defined by US Federal and State Consumer Product Regulations	

10. STABILITY AND REACTIVITY
Conditions to avoid	:	Heat, flames and sparks.
  	
Materials to avoid	:	Strong oxidizing agents
	
Hazardous decomposition products	:	Thermal decomposition can lead to release of irritating gases and vapours.

Hazardous reactions	:	Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION
Acute oral toxicity	:	LD50
estimated
4,103 mg/kg

Acute inhalation toxicity	:	LC50
estimated
> 2.07 mg/l

Acute dermal toxicity	:	LD50
estimated
> 5,000 mg/kg

Chronic effects
Carcinogenicity	:	no data available

Mutagenicity	:	None Anticipated	

Reproductive effects	:	no data available

Teratogenicity	:	no data available

Sensitisation	:	Substance is not a sensitizer.

12. ECOLOGICAL INFORMATION
Ecotoxicity effects	:	no data available	

13. DISPOSAL CONSIDERATIONS
		PESTICIDAL WASTE:
Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal.
Consumer may discard empty container in trash, or recycle where facilities exist.
	
RCRA waste class	:	D001 (Ignitable Waste)

14. TRANSPORT INFORMATION
Land transport
•	U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name	UN 1993 Flammable liquids, N.O.S. 3, III	
Class:	3	
UN number	1993	
Packaging group:III
Note:	Limited quantities derogation may be applicable to this product, please check transport documents.	

Sea transport
•	IMDG:
Proper shipping name	UN 1993 Flammable liquids, N.O.S. 3, III	
Class:	3	
UN number:	1993	
Packaging group:	III	
EmS:F-E, S-E	
Note:	Limited quantities derogation may be applicable to this product, please check transport documents.	

Air transport
•	ICAO/IATA:
Proper shipping name	UN 1993 Flammable liquids, N.O.S. 3, III
Class:	3	
UN/ID No.:	UN 1993	
Packaging group:	III	
Note:	SC Johnson typically does not ship products via air. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air.	

15. REGULATORY INFORMATION
Notification status	:	All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
	
Notification status	:	All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
	
California Prop. 65	:	This product is not subject to the reporting requirements under California's Proposition 65.	
Canada Regulations	:	This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.	

16. OTHER INFORMATION
	HMIS Ratings 
Health	2
	
Flammability	3	
Reactivity	0

NFPA Ratings 
Health	2
	
Fire	3
	
Reactivity	0
	
Special	-

This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by	SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)