1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name	:	OFF!™ FAMILYCARE® INSECT REPELLENT - SMOOTH & DRY (REG. No. 28648 P.C.P. ACT)
	
Use of the Substance/Mixture	:	Insect Repellent
	
Company	:	S.C. Johnson and Son, Limited
1 Webster Street
Brantford   ON   N3T 5R1
  	
Emergency telephone number	:	 24 Hour Transport & Medical Emergency Phone (866) 231-5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666

2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor	:	clear white / aerosol / pleasant	

Immediate Concerns
	:	Warning
FLAMMABLE:
CAUSES EYE IRRITATION.
Keep away from heat, sparks and flame.
Do not puncture or incinerate.
Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst.
Avoid contact with eyes and lips.
Contents under pressure.

Potential Health Effects
Exposure routes	:	Eye, Skin, Inhalation, Ingestion. 
	
Eyes	:	Causes: 
Moderate eye irritation 
	
Skin	:	May cause skin reactions in rare cases. 
Prolonged or repeated contact may dry skin and cause irritation. 
	
Inhalation	:	May cause nose, throat, and lung irritation. 
Inhalation may cause central nervous system effects. 
	
Ingestion	:	May cause irritation to mouth, throat and stomach. 
May cause abdominal discomfort. 
Causes headache, drowsiness or other effects to the central nervous system. 
	
Aggravated Medical Condition	:	Persons with pre-existing skin disorders may be more susceptible to irritating effects. 
Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects 
Do not apply to cuts or irritated skin. 

3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:

Chemical Name	CAS-No.	Weight percent	
Ethyl alcohol	64-17-5	 10.00 - 30.00	
Butane	106-97-8	 10.00 - 30.00	
N,N-Diethyl-m-toluamide	134-62-3	 10.00 - 30.00	
Propane	74-98-6	 10.00 - 30.00	
Isobutane	75-28-5	 10.00 - 30.00	
Corn starch	9005-25-8	 10.00 - 30.00	
Magnesium carbonate	546-93-0	 1.00 - 5.00	
Isopropyl Myristate	110-27-0	 1.00 - 5.00	

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES
Eye contact	:	Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. 
	
Skin contact	:	Wash off immediately with plenty of water. Rinse with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing. 
	
Inhalation	:	Remove to fresh air. If breathing is affected, get medical attention. 
	
Ingestion	:	If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 

5. FIREFIGHTING MEASURES
Suitable extinguishing media	:	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.	

Specific hazards during firefighting	:	Burns with colourless flame. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. 	

Further information	:	Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 	

Flash point	:	< -7 °C
< 19.4 °F
Method: Tag Closed Cup  (TCC)
Note: Propellant
	
Lower explosion limit	:	Note: no data available
	
Upper explosion limit	:	Note: no data available
	
NFPA Classification	:	NFPA Level 2 Aerosol    	

6. ACCIDENTAL RELEASE MEASURES
Personal precautions	:	Remove all sources of ignition.
Wear personal protective equipment.
	
Environmental precautions	:	Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental contamination.
Outside of normal use, avoid release to the environment.
	
Methods for cleaning up	:	If damage occurs to aerosol can:
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

7. HANDLING AND STORAGE
Handling
Advice on safe handling	:	Do not puncture or incinerate.
Avoid contact with eyes and lips.
Avoid breathing vapors, mist or gas.
For personal protection see section 8.
Do not spray toward face.
Do not use in areas without adequate ventilation.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
	
Advice on protection against fire and explosion	:	Keep away from heat and sources of ignition.
Take measures to prevent the build up of electrostatic charge.

Storage
Requirements for storage areas and containers	:	Keep away from food, drink and animal feedingstuffs.
Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst.
Keep in a dry, cool and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components	CAS-No.	mg/m3
 	ppm 
	Non-standard units	Basis	
Ethyl alcohol	64-17-5	-
1,000 ppm
	-
	ACGIH STEL

Butane	106-97-8	-
1,000 ppm
	-
	ACGIH TWA

Propane	74-98-6	-
1,000 ppm
	-
	ACGIH TWA

Isobutane	75-28-5	-
1,000 ppm
	-
	ACGIH TWA

Corn starch	9005-25-8	10 mg/m3
-
	-
	ACGIH TWA

Personal protective equipment
Respiratory protection
		Use only with adequate ventilation.
 Do not spray in enclosed areas.
	
Hand protection
	:	No special requirements.
	
Eye protection
	Safety glasses with side-shields
	
Skin and body protection
:	No special requirements.
	
Hygiene measures	:	Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 

9. PHYSICAL AND CHEMICAL PROPERTIES
Form	:	aerosol
	
Color	:	clear white
	
Odor	:	pleasant
	
pH 	:	not applicable
	
Melting point	:	not applicable
	
Boiling point	:	not applicable
	
Freezing point	:	not applicable
	
Flash point	:	< -7 °C
< 19.4 °F
Method: Tag Closed Cup  (TCC)
Propellant
	
Evaporation rate	:	no data available
	
Flammability (solid, gas) 	:	no data available
	
Autoignition temperature 	:	no data available
	
Lower explosion limit	:	no data available
	
Upper explosion limit	:	no data available
	
Vapour pressure	:	55 psi
at 70 °F
	
Density	:	0.78 g/cm3
	
Water solubility	:	dispersible
	
Partition coefficient: n-octanol/water	:	
no data available
	
Solubility in other solvents	:	not applicable
	
Viscosity, dynamic	:	not applicable
	
Volatile Organic Compounds 
Total VOC (wt. %)*	:	66.7 %	- additional exemptions may apply
*as defined by US Federal and State Consumer Product Regulations	

10. STABILITY AND REACTIVITY
Conditions to avoid	:	Heat, flames and sparks.
  	
Materials to avoid	:	Strong oxidizing agents
	
Hazardous decomposition products	:	Thermal decomposition can lead to release of irritating gases and vapours.

Hazardous reactions	:	Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION
Acute oral toxicity	:	LD50
Calculated
3,735 mg/kg

Acute inhalation toxicity	:	LC50
Calculated
> 2.79 mg/l

Acute dermal toxicity	:	LD50
estimated
> 2,000 mg/kg

Chronic effects
Carcinogenicity	:	no data available

Mutagenicity	:	no data available

Reproductive effects	:	no data available

Teratogenicity	:	no data available

Sensitisation	:	Not known to be a sensitizer.

12. ECOLOGICAL INFORMATION
Ecotoxicity effects	:	no data available	

13. DISPOSAL CONSIDERATIONS
		PESTICIDAL WASTE:
Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal.
Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION
Land transport
•	U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name	UN 1950 AEROSOLS, Flammable, 2.1	
Class:	2.1	
UN number	1950	
Packaging group:None. 
Note:	Limited quantities derogation may be applicable to this product, please check transport documents.	

Sea transport
•	IMDG:
Proper shipping name	UN 1950 AEROSOLS, Flammable, 2.1	
Class:	2	
UN number:	1950	
Packaging group:	None.  	
EmS:F-D, S-U	
Note:	Limited quantities derogation may be applicable to this product, please check transport documents.	

Air transport
•	ICAO/IATA:
Proper shipping name	UN 1950 AEROSOLS, Flammable, 2.1
Class:	2.1	
UN/ID No.:	UN 1950	
Packaging group:	None.	
Note:	SC Johnson typically does not ship products via air. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air.	

15. REGULATORY INFORMATION
Notification status	:	All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
	
Notification status	:	All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
	
California Prop. 65	:	This product is not subject to the reporting requirements under California's Proposition 65.	
Canada Regulations	:	This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.	

16. OTHER INFORMATION
	HMIS Ratings 
Health	2
	
Flammability	4	
Reactivity	0

NFPA Ratings 
Health	2
	
Fire	4
	
Reactivity	0
	
Special	-

Further information
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by:	SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)