1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name	:	OFF! Clip-on® Mosquito Repellent REG No.30211 P.C.P.Act 
	
Use of the Substance/Mixture	:	Insect Repellent
	
Company	:	S.C. Johnson and Son, Limited
1 Webster Street
Brantford   ON   N3T 5R1
  	
Emergency telephone number	:	 24 Hour Transport & Medical Emergency Phone (866) 231-5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666

2. HAZARDS IDENTIFICATION
Emergency OverviewAppearance / Odor	:	white / Liquid absorbed by inert carrier material / characteristic	

Immediate Concerns
	:	Caution
May be harmful if inhaled.
Avoid contact with skin, eyes and clothing.
Avoid breathing vapours, mist or gas.
Harmful in contact with skin and if swallowed.

Potential Health Effects
Exposure routes	:	Eye, Skin, Inhalation, Ingestion. 
	
Eyes	:	No adverse effects expected when used as directed. 
	
Skin	:	May cause skin irritation. 
May cause transient tingling and reddening of the skin. 
May be harmful if absorbed through skin. 
	
Inhalation	:	Inhalation may cause central nervous system effects. 
	
Ingestion	:	May cause irritation to mouth, throat and stomach. 
May cause abdominal discomfort. 
May be harmful if swallowed. 
	
Aggravated Medical Condition	:	Persons with pre-existing skin disorders may be more susceptible to irritating effects. 

3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:

Chemical Name	CAS-No.	Weight percent	
Metofluthrin	240494-70-6	 15.00 - 40.00	

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES
Eye contact	:	Flush immediately with plenty of water for at least 15 to 20 minutes. Remove contact lenses. Get medical attention if irritation develops and persists. 
	
Skin contact	:	Remove contaminated clothing and shoes. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Wash contaminated clothing before reuse. 
	
Inhalation	:	Remove to fresh air. If breathing is affected, get medical attention. 
	
Ingestion	:	If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 

5. FIREFIGHTING MEASURES
Suitable extinguishing media	:	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.	

Specific hazards during firefighting	:	Do not allow run-off from fire fighting to enter drains or water courses. Material may burn in heat of fire. 	

Further information	:	Fight fire from maximum distance or protected area. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 	

Flash point	:	Note: Not applicable
	
Lower explosion limit	:	Note: No data available
	
Upper explosion limit	:	Note: No data available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions	:	Wear personal protective equipment.
	
Environmental precautions	:	Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental contamination.
Outside of normal use, avoid release to the environment.
	
Methods for cleaning up	:	Sweep up and shovel into suitable containers for disposal.
Clean residue from spill site.

7. HANDLING AND STORAGE
Handling
Advice on safe handling	:	Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Smoking, eating and drinking should be prohibited in the application area.
Avoid contact with skin, eyes and clothing.
Avoid breathing vapours, mist or gas.
	
Advice on protection against fire and explosion	:	Normal measures for preventive fire protection.
Keep away from heat and sources of ignition.

Storage
Requirements for storage areas and containers	:	Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above.
Occupational Exposure Limits

Personal protective equipment
Respiratory protection
		No personal respiratory protective equipment normally required.
	
Hand protection
	:	For prolonged or repeated contact use protective gloves.
	
Eye protection
	No special requirements.
	
Skin and body protection
:	No special requirements.
	
Hygiene measures	:	Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. 

9. PHYSICAL AND CHEMICAL PROPERTIES
Form	:	Liquid absorbed by inert carrier material
	
Color	:	white
	
Odor	:	characteristic
	
pH 	:	No data available
	
Melting point	:	No data available
	
Boiling point	:	No data available
	
Freezing point	:	No data available
	
Flash point	:	Not applicable
	
Evaporation rate	:	No data available
	
Flammability (solid, gas) 	:	No data available
	
Auto-ignition temperature 	:	No data available
	
Lower explosion limit	:	No data available
	
Upper explosion limit	:	No data available
	
Vapour pressure	:	No data available
	
Density	:	No data available
	
Water solubility	:	No data available
	
Partition coefficient: n-octanol/water	:	
No data available
	
Viscosity, dynamic	:	No data available
	
Viscosity, kinematic	:	No data available
	
Relative vapour density	:	No data available

Volatile Organic Compounds 
Total VOC (wt. %)*	:	1.1 %	- additional exemptions may apply
*as defined by US Federal and State Consumer Product Regulations	

10. STABILITY AND REACTIVITY
Conditions to avoid	:	Direct sources of heat.
  	
Materials to avoid	:	Avoid contact with:
Bases
	
Hazardous decomposition products	:	Thermal decomposition can lead to release of irritating gases and vapours.

Thermal decomposition	:	Note: No data available
	
Hazardous reactions	:	Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION
Acute oral toxicity	:	LD50
estimated
> 2,000 mg/kg

Acute inhalation toxicity	:	LC50
estimated
1.08 - 1.96 mg/l

Acute dermal toxicity	:	LD50
estimated
> 2,000 mg/kg

Chronic effects
Carcinogenicity	:	None Anticipated	

Mutagenicity	:	None Anticipated	

Reproductive effects	:	None Anticipated

Teratogenicity	:	None Anticipated

Sensitisation	:	Not known to be a sensitizer.

12. ECOLOGICAL INFORMATION
Ecotoxicity effects	:	Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.	

13. DISPOSAL CONSIDERATIONS
		PESTICIDAL WASTE:
Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal.
Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION
Land transport
•	U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name	UN 3077 Environmentally Hazardous Substance, Solid, N.O.S., (Metofluthrin) 9, III, LTD QTY	
Class:	9	
UN number	3077	
Packaging group:III

Sea transport
•	IMDG:
Proper shipping name	UN 3077 Environmentally Hazardous Substance, Solid, N.O.S., (Metofluthrin) 9, III, LTD QTY	
Class:	9	
UN number:	3077	
Packaging group:	III	
EmS:F-A, S-F	

Air transport
•	ICAO/IATA:
Proper shipping name	UN 3077 Environmentally Hazardous Substance, Solid, N.O.S., (Metofluthrin) 9, III, LTD QTY
Class:	9	
UN/ID No.:	UN 3077	
Packaging group:	III	

15. REGULATORY INFORMATION
Notification status	:	All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
	
Notification status	:	All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
	
California Prop. 65	:	This product is not subject to the reporting requirements under California's Proposition 65.	
Canada Regulations	:	This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.	

16. OTHER INFORMATION
	HMIS Ratings 
Health	2
	
Flammability	1	
Reactivity	0

NFPA Ratings 
Health	2
	
Fire	1
	
Reactivity	0
	
Special	-

This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by	SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)